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Technical Paper

Impact of Sulphur on the NOx Trap Catalyst Activity-Poisoning and Regeneration Behaviour

2000-06-19
2000-01-1874
This presented paper deals with NOx trap sulphur poisoning and its regeneration. Sulphur poisoning has been studied with different SO2 gas concentrations under laboratory and engine test bench conditions. The sulphur poisoning studies have shown that the different NOx-traps available in the market have different behaviours toward SO2 poisoning and are all very sensitive to it. The results outline a non linear relationship of the NOx trap sulphur poisoning as a function of SO2 concentration. For instance, engine bench tests show that with a 50 and a 110ppm sulphur containing gasoline, a decrease of 50% in the NOx-trap storage capacity is respectively observed after 20 and 15 hours. With a gasoline containing 20ppm of sulphur, the same deactivation level is observed after 90 hours.
Technical Paper

Influence of Both Catalyst Geometry and Fuel Sulfur Content on NOX Adsorber Poisoning

2001-05-07
2001-01-1934
NOx adsorbers are very sensitive to sulfur poisoning and future fuel standards are unlikely to be sufficient to prevent the system from requiring periodic desulfation procedures. The purpose of this paper is to present the effects of low fuel sulfur content such as 50 ppm and 10 ppm on the NOx adsorber efficiency for a diesel application. Through this study, the influence of the substrate cell geometry has also been assessed. The use of a 10 ppm sulfur fuel is not enough to maintain, at a high level, the NOx adsorber performance during a 40,000 km aging test. The desulfation criterion (efficiency loss of 30%) is reached after the first 16,000 km. However, the desulfation operation is not enough to recover the initial catalyst performance and the poisoning velocity increases as the catalyst ages. The hexagonal cell substrate catalyst is less sensitive to sulfur poisoning than a square cell substrate catalyst so that its desulfation frequency is much lower.
Technical Paper

Intake System Diagnosis for Diesel Engine with Dual-Loop EGR

2012-04-16
2012-01-0904
This paper proposes a method to detect an intake manifold leakage for a Diesel engine with a dual loop EGR system. The intake manifold leak has a strong impact on the engine performances by changing the intake manifold burned gas ratio. This fault is analyzed according to the control structure used and also according to the EGR operating mode. The paper proposes a diagnosis algorithm to detect the intake manifold leak in sequential or simultaneous use of the two EGR paths. The sensors considered are the mass air flow meter, the intake manifold pressure sensor, the exhaust equivalence ratio sensor and the differential pressure sensor (across the HP EGR valve). The diagnosis is based on a criteria that uses the redundancy between these sensors and air system models or estimators. The diagnosis threshold depends on the engine operating conditions as well as the sensor or model dispersions.
Technical Paper

Investigation of Gravel Noise Mechanisms and Impact Noise Transfer

2007-05-15
2007-01-2274
Impact noise, inside a car, due to tire-launched gravel on the road can lead to loss of quality perception. Gravel noise is mainly caused by small-sized particles which are too small to be seen on the road by the driver. The investigation focuses on the identification of the mechanisms of excitation and transfer. The spatial distribution of the particles flying from a tire is determined, as well as the probable impact locations on the vehicle body-panels. Finally the relative noise contributions of the body-panels are estimated by adding the panel-to-ear transfer functions. This form of Transfer-Path-Analysis allows vehicle optimization and target setting on the level of the tires, exterior panel treatment and isolation.
Journal Article

Investigation on Multiple Injection Strategies for Gasoline PPC Operation in a Newly Designed 2-Stroke HSDI Compression Ignition Engine

2015-04-14
2015-01-0830
Partially Premixed Combustion (PPC) of fuels in the gasoline octane range has proven its potential to achieve simultaneous reduction in soot and NOX emissions, combined with high indicated efficiencies; while still retaining proper control over combustion phasing with the injection event, contrary to fully premixed strategies. However, gasoline fuels with high octane number as the commonly available for the public provide a challenge to ensure reliable ignition especially in the low load range, while fuel blends with lower octane numbers present problems for extending the ignition delay in the high load range and avoid the onset of knocking-like combustion. Thus, choosing an appropriate fuel and injection strategy is critical to solve these issues, assuring successful PPC operation in the full engine map.
Technical Paper

NOx-Trap System Development and Characterization for Diesel Engines Emission Control

2000-10-16
2000-01-2910
Laboratory and vehicle tests were carried out to investigate behaviour and potentiality of NOx-trap catalytic system in Diesel conditions. Three main aspects were studied. The first one deals with the NOx storage capacity of adsorber under laboratory and vehicle conditions, especially regarding the influence of driving conditions. The second one focuses on the regenerability of different materials. At length, special attention is devoted to the sulphur poisoning rate. A representative laboratory test method was built up, to evaluate NOx storage capacity under Diesel conditions. It is shown that NOx adsorption occurs from 100 to 400°C. Low temperature activity (100 to 250°C) is conditioned by low NOx flow emission, mainly due to the use of high EGR rate. Higher temperatures lead to an increase in the intrinsic NOx Storage capacity of the material, but are also accompanied by high NOx concentration and space velocity.
Technical Paper

Non-Thermal Plasma Assisted Catalytic NOx Remediation from a Lean Model Exhaust

2001-09-24
2001-01-3508
No efficient catalyst presently exists for deNOx in lean burn conditions. Furthermore, actual catalysts generally deactivate during reaction. A cylindrical DBD non-thermal plasma reactor was coupled with a stable three-function catalyst in order to verify the nature of the effect of the plasma on the catalytic process. A mixture of NO/O2/C3H6 in N2 was used as a lean model exhaust. The plasma was found to perform two of the three functions: NO oxidation to NO2 and propene activation through the partial oxidation of the hydrocarbon to aldehyde or alcohol. A complete catalyst containing the first two previous functions and the associative chemisorption of NO (third function) was used, as well as a simplified catalyst containing only the third function. Results suggest an advantageous plasma-catalyst coupling effect on NOx remediation in accordance with the proposed catalytic model.
Technical Paper

Optimal Control of Mass Transport Time-Delay Model in an EGR

2020-04-14
2020-01-0251
This paper touches on the mass transport phenomenon in the exhaust gas recirculation (EGR) of a gasoline engine air path. It presents the control-oriented model and control design of the burned gas ratio (BGR) transport phenomenon, witnessed in the intake path of an internal combustion engine (ICE), due to the redirection of burned gases to the intake path by the low-pressure EGR (LP-EGR). Based on a nonlinear AMESim® model of the engine, the BGR in the intake manifold is modeled as a state-space (SS) output time-delay model, or alternatively as an ODE-PDE coupled system, that take into account the time delay between the moment at which the combusted gases leave the exhaust manifold and that at which they are readmitted in the intake manifold. In addition to their mass transport delay, the BGRs in the intake path are also subject to state and input inequality constraints.
Technical Paper

Progress in Diesel HCCI Combustion Within the European SPACE LIGHT Project

2004-06-08
2004-01-1904
The purpose of the European « SPACE LIGHT » (Whole SPACE combustion for LIGHT duty diesel vehicles) 3-year project launched in 2001 is to research and develop an innovative Homogeneous internal mixture Charged Compression Ignition (HCCI) for passenger cars diesel engine where the combustion process can take place simultaneously in the whole SPACE of the combustion chamber while providing almost no NOx and particulates emissions. This paper presents the whole project with the main R&D tasks necessary to comply with the industrial and technical objectives of the project. The research approach adopted is briefly described. It is then followed by a detailed description of the most recent progress achieved during the tasks recently undertaken. The methodology adopted starts from the research study of the in-cylinder combustion specifications necessary to achieve HCCI combustion from experimental single cylinder engines testing in premixed charged conditions.
Technical Paper

Repeatability of Fine Particle Measurement of Diesel and Gasoline Vehicles Exhaust Gas

2004-06-08
2004-01-1983
Four Diesel vehicles and two gasoline ones are used to determine the repeatability of the particle number and size measurements. Two analytical techniques are used: Scanning Mobility Particle Sizer (SMPS) and Electrical Low Pressure Impactor (ELPI). The influence of technology (Euro2 and Euro3, Diesel and gasoline vehicles, Diesel Particulate Filter (DPF), Gasoline Direct Injection (GDI)) and speed on the particle number and size is presented in the case of steady speeds and the European Driving Cycle (EDC). The repeatability of these measurements is determined at the entire particle distribution. The global 1.96*Standard Deviation (SD) of the median diameter, determined by SMPS, is 8 nm. The median diameter is difficult to be determined in several cases due to the flat profiles of the emitted particles. The global 1.96*Relative Standard Deviation (RSD) of the particle number presents a U-like curve, with a minimum value (55-57%) at about 100 nm.
Technical Paper

Semi-Empirical 0D Modeling for Engine-Out Soot Emission Prediction in D.I. Diesel Engines

2016-04-05
2016-01-0562
Due to its harmful effect on both human health and environment, soot emission is considered as one of the most important diesel engine pollutants. In the last decades, the industrial engine manufacturers have been able to strongly reduce its engine-out value by many different techniques, in order to respect the stricter emission norms. Simulation modeling has played and continues to play a key role for this purpose in the engine control system development. In this context, this paper proposes a new soot emission model for a direct injection diesel engine. This soot model is based on a zero-dimensional semi-physical approach coupled with a crank-angle resolved combustion model and a thermodynamic calculation of the burned gas products temperature. Furthermore, a multi linear regression model has been used to estimate the soot emissions as function of significant physical combustion parameters.
Technical Paper

System Approach for NOx Reduction: Double LNT Diesel After-Treatment Architecture

2011-04-12
2011-01-1300
This paper presents an after-treatment architecture combining a close coupled NOx trap and an under floor NOx trap. Instead of simply increasing the volume of the catalyst, we propose to broaden the active temperature window by splitting the LNT along the exhaust line. In order to design this architecture, a complete 1D model of NOx trap has been developed. Validated with respect to experimental data, this model has been useful to define the two volumes of LNT, making significant savings on the test bench exploitation. However, one of the main difficulties to operate the proposed architecture is the NOx purge and sulfur poisoning management. In order to optimize the NOx and sulfur purge launches, we have developed a control strategy based on an embedded reduced LNT model. These strategies have been validated on different driving cycles, by the means of simulation and of vehicle tests using rapid prototyping tools.
Technical Paper

The Potential of Highly Premixed Combustion for Pollutant Control in an Automotive Two-Stroke HSDI Diesel Engine

2012-04-16
2012-01-1104
An innovative alternative to overcome the load limits of the early injection highly premixed combustion concept consists of taking advantage of the intrinsic characteristics of two-stroke engines, since they can attain the full load torque of a four-stroke engine as the addition of two medium load cycles, where the implementation of this combustion concept could be promising. In this frame, the main objective of this investigation focuses on evaluating the potential of the early injection HPC concept using a conventional diesel fuel combined with a two-stroke poppet valves engine architecture for pollutant control, while keeping a competitive engine efficiency. On a first stage, the HPC concept was implemented at low engine load, where the concept is expected to provide the best results, by advancing the start of injection towards the compression stroke and it was confirmed how it is possible to reduce NOX and soot emissions, but increasing HC and CO emissions.
Technical Paper

Well-to-Wheels Analysis of Future Automotive Fuels and Powertrains in the European Context

2004-06-08
2004-01-1924
A consortium of CONCAWE, EUCAR and the EU Commission's JRC carried out a Well-to-Wheels analysis of a wide range of automotive fuels and powertrains. The study gives an assessment of the energy consumption and greenhouse gas emissions for each pathway. It also considers macroeconomic costs and the market potential of alternative fuels.
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